K. V. Tsys, M. G. Chegerev, G. K. Fukin, A. V. Piskunov, “Stable O,N-heterocyclic plumbylenes bearing sterically hindered <i>o</i>-amidophenolate ligands”, Mendeleev Commun., 2018, Volume 28, Issue 5,Pages <nobr>527

This article is cited in 27 papers

Communications

Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands

K. V. Tsys^a, M. G. Chegerev^ab, G. K. Fukin^a, A. V. Piskunov^a

^a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Abstract: The reaction of dilithium salts of 4,6-di-tert-butyl-N-(R)-o-aminophenols with PbCl₂ leads to the formation of new O,N-heterocyclic plumbylenes [R is Bu^t or dipp (2,6-diiso-propylphenyl)]. Both compounds possess dimeric structure in crystals according to the X-ray analysis of a single crystal. The formation of unstable paramagnetic plumbylene was detected during an oxidation of 4,6-di-tert-butyl-N-(tert-butyl)-o-aminophenolatolead(II) with HgBr₂.

Language: English

DOI: 10.1016/j.mencom.2018.09.026

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