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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 5, Pages 536–537 (Mi mendc1827)

This article is cited in 7 papers

Communications

In situ EPR study of chemoselective hydrogenation of nitroarenes on Au/Al2O3 catalyst

S. S. Yakushkina, A. L. Nuzhdina, E. A. Artiukhaa, P. E. Plyusninb, G. A. Bukhtiyarovaa, O. N. Martyanova

a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Detected by the in situ EPR spectroscopy immobilized nitro radical anions generated in the course of Au/Al2O3-catalyzed nitrobenzene hydrogenation demonstrate the abnormal hyper-fine splitting and serve as intermediates of the reaction.

Language: English

DOI: 10.1016/j.mencom.2018.09.029



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