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JOURNALS
// Mendeleev Communications
// Archive
Mendeleev Commun.,
2018
Volume 28,
Issue 5,
Pages
536–537
(Mi mendc1827)
This article is cited in
7
papers
Communications
In situ
EPR study of chemoselective hydrogenation of nitroarenes on Au/Al
2
O
3
catalyst
S. S. Yakushkin
a
,
A. L. Nuzhdin
a
,
E. A. Artiukha
a
,
P. E. Plyusnin
b
,
G. A. Bukhtiyarova
a
,
O. N. Martyanov
a
a
G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b
A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract:
Detected by the
in situ
EPR spectroscopy immobilized nitro radical anions generated in the course of Au/Al
2
O
3
-catalyzed nitrobenzene hydrogenation demonstrate the abnormal hyper-fine splitting and serve as intermediates of the reaction.
Language:
English
DOI:
10.1016/j.mencom.2018.09.029
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Supplementary materials:
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