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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 5, Pages 543–545 (Mi mendc1830)

This article is cited in 7 papers

Communications

Annelated tricyclic thiophenes and their photophysical properties

E. V. Lukovskayaa, N. V. Dyachenkoa, A. V. Khoroshutina, A. A. Bobylevaa, A. V. Anisimova, V. A. Karnoukhovab, G. Jonusauskasc, Yu. V. Fedorovb, O. A. Fedorovaab

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c Centre de Physique Moléculaire Optique et Hetzienne, University Bordeaux 1, France

Abstract: Photochemical oxidative cyclization of 3-[(E)-2-(3,4-di-methoxyphenyl)vinyl]thiophene and its 15-crown-5-analogue (15-[(E)-2-(3-thienyl)vinyl]-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine) affords the isomeric thiophene-containing fused aromatic compounds demonstrating photophysical properties different from those of initial styryl derivatives. E-Configuration of the initial styryl dye, 3-[(E)-2-(3,4-dimethoxyphenyl)vinyl]thiophene, has been proved by X-ray analysis.

Language: English

DOI: 10.1016/j.mencom.2018.09.032



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