N. S. Bushkov, A. V. Rumyantsev, A. A. Zhizhin, I. A. Godovikov, P. A. Zhizhko, D. N. Zarubin, “Ti-catalyzed heterometathetical condensation of <i>N-</i>sulfinylamines into sulfurdiimines”, Mendeleev Commun., 2024, Volume 34, Issue 4,Pages <nobr>555

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Communications

Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines

N. S. Bushkov^a, A. V. Rumyantsev^ab, A. A. Zhizhin^a, I. A. Godovikov^a, P. A. Zhizhko^a, D. N. Zarubin^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Well-defined silica-supported Ti imido complex (≡SiO)Ti(=NBu^t)(Me₂Pyr)(Py)₂ (Me₂Pyr = 2,5-dimethyl- pyrrolyl) catalyzes condensation of N-sulfinylanilines into sulfurdiimines via the oxo/imido heterometathesis providing a convenient synthetic route to functionalized sulfurdiimines.

Keywords: imido complexes, titanium complexes, imides, metathesis, heterometathesis, N-sulfinylamine, sulfurdiimine.

Language: English

DOI: 10.1016/j.mencom.2024.06.028

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