T. R. Akmalov, S. M. Masoud, D. A. Petropavlovskikh, M. A. Zotova, S. E. Nefedov, S. N. Osipov, “New olefin metathesis catalysts with fluorinated unsymmetrical imidazole-based ligands”, Mendeleev Commun., 2018, Volume 28, Issue 6,Pages <nobr>609–611</nobr>

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Mendeleev Commun., 2018 Volume 28, Issue 6, Pages 609–611 (Mi mendc1852)

This article is cited in 8 papers

Communications

New olefin metathesis catalysts with fluorinated unsymmetrical imidazole-based ligands

T. R. Akmalov^a, S. M. Masoud^a, D. A. Petropavlovskikh^a, M. A. Zotova^b, S. E. Nefedov^c, S. N. Osipov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New olefin metathesis catalysts, unsaturated analogues of the Grubbs II and Hoveyda–Grubbs II ones, bearing bulky (alkoxy)hexafluoroisopropyl groups in one of the aryl substituent of NHC ligand provide high conversions in model ring closing metathesis of diallyl- and allylmethallylmalonates.

Language: English

DOI: 10.1016/j.mencom.2018.11.015

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