I. E. Nifant'ev, A. V. Shlyakhtin, V. V. Bagrov, R. N. Ezhov, B. A. Lozhkin, A. V. Churakov, P. V. Ivchenko, “Ring-opened 4-hydroxy-δ-valerolactone subunit as a key structural fragment of polyesters that degrade without acid formation”, Mendeleev Commun., 2018, Volume 28, Issue 6,Pages <nobr>629–631</nobr>

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Mendeleev Commun., 2018 Volume 28, Issue 6, Pages 629–631 (Mi mendc1859)

This article is cited in 5 papers

Communications

Ring-opened 4-hydroxy-δ-valerolactone subunit as a key structural fragment of polyesters that degrade without acid formation

I. E. Nifant'ev^ab, A. V. Shlyakhtin^a, V. V. Bagrov^a, R. N. Ezhov^a, B. A. Lozhkin^a, A. V. Churakov^c, P. V. Ivchenko^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Random copolymers of ɛ-caprolactone with O-benzyl-protected 4-hydroxy- or 2,4-dihydroxy-δ-valerolactone after hydrogenation form γ-hydroxy functionalized polyesters that degrade via the cyclization to γ-butyrolactone fragments without carboxylic acid formation.

Language: English

DOI: 10.1016/j.mencom.2018.11.022

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