I. A. Efimenko, O. S. Erofeeva, E. A. Ugolkova, N. N. Efimov, L. I. Demina, P. V. Grishanova, V. V. Minin, “Paramagnetic Pd<sup>+</sup> centers in the polymeric matrices of palladium(I) sorbates and 4-pentenate”, Mendeleev Commun., 2018, Volume 28, Issue 6,Pages <nobr>632

This article is cited in 3 papers

Communications

Paramagnetic Pd⁺ centers in the polymeric matrices of palladium(I) sorbates and 4-pentenate

I. A. Efimenko^a, O. S. Erofeeva^a, E. A. Ugolkova^a, N. N. Efimov^a, L. I. Demina^b, P. V. Grishanova^a, V. V. Minin^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The paramagnetic Pd^I centers with unpaired electrons have been first revealed by EPR spectroscopy in the polymeric matrices of Pd^I sorbates [Pd(C₆H₇O₂)H₂O]_n, [Pd(C₆H₇O₂)]_n and 4-pentenate [Pd(C₅H₇O₂)H₂O]_n. These compounds have been obtained by the reactions between Pd₃(MeCO₂)₆ and sorbic (MeCH=CHCH=CHCOOH) and 4-pentenoic (CH₂=CHCH₂CH₂COOH) acids in MeOH.

Language: English

DOI: 10.1016/j.mencom.2018.11.023