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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2017 Volume 27, Issue 1, Pages 29–30 (Mi mendc1885)

This article is cited in 4 papers

Communications

Transformation of cyclic ketimines to oxaziridines and nitrones

N. G. Voznesenskaya, O. I. Shmatova, V. G. Nenajdenko

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Treatment of 5-, 6- and 7-membered cyclic ketimines bearing alkyl or aryl group with m-chloroperbenzoic acid proceeds as C=N epoxidation and affords bicyclic oxaziridines in good yields, whose subsequent rearrangement gives nitrones.

Language: English

DOI: 10.1016/j.mencom.2017.01.008



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