V. P. Zelenov, S. S. Bukalov, L. A. Leites, R. R. Aysin, A. N. Subbotin, M. I. Struchkova, I. V. Fedyanin, “Trifluoroacetyl nitrate”, Mendeleev Commun., 2017, Volume 27, Issue 1,Pages <nobr>31

This article is cited in 13 papers

Communications

Trifluoroacetyl nitrate

V. P. Zelenov^a, S. S. Bukalov^b, L. A. Leites^b, R. R. Aysin^b, A. N. Subbotin^a, M. I. Struchkova^a, I. V. Fedyanin^b

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Individual trifluoroacetyl nitrate (TFAN) was synthesized by the reaction of N₂O₅ with trifluoroacetic anhydride (TFAA) and was characterized by ¹³C, ¹⁴N, ¹⁵N, and ¹⁹F NMR and Raman spectroscopy. In the gas phase TFAN partially decomposes into N₂O₅ and TFAA, and in solutions the equilibrium is shifted to TFAN. Mono nitration of [2.2]paracyclophane with TFAN proceeds in good yields.

Language: English

DOI: 10.1016/j.mencom.2017.01.009

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