I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, S. I. Bezzubov, P. V. Ivchenko, “Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’”, Mendeleev Commun., 2017, Volume 27, Issue 1,Pages <nobr>35

This article is cited in 19 papers

Communications

Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’

I. E. Nifant'ev^ab, A. A. Vinogradov^b, A. A. Vinogradov^b, S. I. Bezzubov^c, P. V. Ivchenko^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.

Language: English

DOI: 10.1016/j.mencom.2017.01.010

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