A. D. Kirilin, L. O. Belova, M. V. Pletneva, N. A. Golub, P. A. Storozhenko, N. I. Kirilina, “New aspects of isocyanate synthesis with the use of <i>O</i>-silylurethanes”, Mendeleev Commun., 2017, Volume 27, Issue 1,Pages <nobr>99–100</nobr>

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Mendeleev Commun., 2017 Volume 27, Issue 1, Pages 99–100 (Mi mendc1910)

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Communications

New aspects of isocyanate synthesis with the use of O-silylurethanes

A. D. Kirilin^a, L. O. Belova^a, M. V. Pletneva^a, N. A. Golub^a, P. A. Storozhenko^b, N. I. Kirilina^b

^a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
^b State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation

Abstract: Silyl group at the nitrogen atom in the O-silylurethanes drastically affects the thermolysis processes and allows one to simplify the synthesis of methyl- and trimethylsilyl isocyanates.

Language: English

DOI: 10.1016/j.mencom.2017.01.033

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