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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2017 Volume 27, Issue 2, Pages 119–121 (Mi mendc1915)

This article is cited in 11 papers

Communications

Synthesis of sarcodictyin A analogue containing 14-methyl group and C(12)=C(13) bond in ring A from levoglucosenone

B. T. Sharipov, A. A. Pershin, F. A. Valeev

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Starting from levoglucosenone piperilene Diels–Alder adduct a total synthesis of sarcodictyin A analogue containing 14-methyl group and C(12)=C(13) bond in ring A was performed, where the key step was the intramolecular cyclization between acetylene and aldehyde moieties to produce a 10-membered carbocycle.

Language: English

DOI: 10.1016/j.mencom.2017.03.003



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