A. V. Artem'ev, A. O. Sutyrina, E. A. Matveeva, A. I. Albanov, L. V. Klyba, “Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus <i>via</i> the Trofimov–Gusarova reaction”, Mendeleev Commun., 2017, Volume 27, Issue 2,Pages <nobr>137

This article is cited in 7 papers

Communications

Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction

A. V. Artem'ev^a, A. O. Sutyrina^b, E. A. Matveeva^b, A. I. Albanov^b, L. V. Klyba^b

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: trans,trans-1,4-Diphenylbuta-1,3-diene reacts with elemental (red) phosphorus in the superbasic KOH / DMSO (H₂O) system (120°C, 3 h) to give, after acidic work-up, 1,4-diphenylbutylphosphinic acid in 48% yield.

Language: English

DOI: 10.1016/j.mencom.2017.03.009

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