M. G. Kostenko, S. V. Sharf, A. A. Rempel, “Structural model of order–order transition state in titanium monoxide TiO<sub>1.0</sub>”, Mendeleev Commun., 2017, Volume 27, Issue 3,Pages <nobr>251

This article is cited in 5 papers

Communications

Structural model of order–order transition state in titanium monoxide TiO_1.0

M. G. Kostenko^a, S. V. Sharf^b, A. A. Rempel^a

^a Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^b Institute of Mathematics and Mechanics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Abstract: A new class of structures, in which vacancies or other point defects of the crystal lattice occupy the sites of two different superstructures simultaneously, is presented using atomic vacancy ordering in titanium monoxide. One of the superstructures is that of the low temperature phase and the other one is additional superstructure yielding an increase in the configurational entropy of ordered state at high temperatures.

Language: English

DOI: 10.1016/j.mencom.2017.05.011

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