E. V. Shuvalova, O. A. Kirichenko, “Hydrogenation of dinitrobenzenes over titania-supported palladium nanoparticles”, Mendeleev Commun., 2024, Volume 34, Issue 4,Pages <nobr>587

This article is cited in 1 paper

Communications

Hydrogenation of dinitrobenzenes over titania-supported palladium nanoparticles

E. V. Shuvalova, O. A. Kirichenko

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Catalysts of 1% Pd/TiO₂ type were prepared via the deposition–precipitation of Pd polyhydroxo complexes followed by reduction with hydrogen at 23 °C. These catalysts were found to be active for the selective hydrogenation of m-dinitrobenzene into m-phenylenediamine at 25–50 °C and 0.5 MPa H₂ in a batch reactor.

Keywords: hydrogenation, dinitrobenzene, phenylenediamine, Pd/TiO₂ catalysts, hydrogen.

Language: English

DOI: 10.1016/j.mencom.2024.06.039

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