RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2017 Volume 27, Issue 3, Pages 260–262 (Mi mendc1961)

This article is cited in 6 papers

Communications

Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation

E. F. Chernovaab, A. S. Ovsyannikovac, S. Ferlayb, S. E. Solovievaac, I. S. Antipinac, A. I. Konovalovac, N. Kyritsakasb, M. W. Hosseinib

a A.M. Butlerov Chemistry Institute, Kazan Federal University, Kazan, Russian Federation
b Molecular Tectonics Laboratory, University of Strasbourg, Strasbourg, France
c A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Depending on the anion ($\mathrm{NO_3^-}$ or $\mathrm{BF_4^-}$) and stoichiometry, the combinations of [1.1.1.1]metacyclophane adopting a blocked 1,3-alternate conformation and bearing four cyanomethylene groups with silver cations under self-assembly conditions lead to the formation of either a 1D coordination network or a discrete binuclear metallomacrocycle.

Language: English

DOI: 10.1016/j.mencom.2017.05.014



© Steklov Math. Inst. of RAS, 2025