V. V. Astakhova, M. Yu. Moskalik, I. V. Sterkhova, B. A. Shainyan, “Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene”, Mendeleev Commun., 2017, Volume 27, Issue 3,Pages <nobr>293

This article is cited in 9 papers

Communications

Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene

V. V. Astakhova, M. Yu. Moskalik, I. V. Sterkhova, B. A. Shainyan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Oxidative addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene leads to N,N’-[(2E)-2,3-dimethylbut-2-ene-1,4-diyl]bis(trifluoroacetamide) and [(2RS,3SR)-N-(2,3-dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide. A tentative mechanism is proposed.

Language: English

DOI: 10.1016/j.mencom.2017.05.026

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