Yu. N. Kononevich, A. A. Anisimov, A. A. Korlyukov, U. S. Tsareva, O. I. Shchegolikhina, A. M. Muzafarov, “Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands”, Mendeleev Commun., 2017, Volume 27, Issue 4,Pages <nobr>332

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Communications

Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands

Yu. N. Kononevich^a, A. A. Anisimov^a, A. A. Korlyukov^ab, U. S. Tsareva^a, O. I. Shchegolikhina^a, A. M. Muzafarov^ac

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.I. Pirogov Russian National Research Medical University, Moscow, Russian Federation
^c N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Two new polyherdal copper metallasiloxanes with pyridine ligands were synthesized by the hydrolysis of triethoxyphenylsilane in the presence of NaOH and the subsequent interaction of the alkaline salt thus in situ formed with CuCl or CuCl₂ in pyridine media. Depending on the salt used, tetra- or pentanuclear sandwich-like Cu-metallasiloxanes were obtained, whose structures were studied by single crystal X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2017.07.002