V. P. Zelenov, S. S. Bukalov, A. N. Subbotin, “A new type of the dinitrogen pentoxide–acid interaction”, Mendeleev Commun., 2017, Volume 27, Issue 4,Pages <nobr>355

This article is cited in 7 papers

Communications

A new type of the dinitrogen pentoxide–acid interaction

V. P. Zelenov^a, S. S. Bukalov^b, A. N. Subbotin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Dinitrogen pentoxide solution in trifluoroacetic acid simultaneously has features of both known types of its interaction with acids, viz. with weak and strong acids. It partially reacts with CF₃COOH to give the covalent trifluoroacetyl nitrate and nitric acid, however the major part of N₂O₅ exists in the covalent form in solution to concurrently produce nitronium ions due to the presence of HNO₃. Quantum chemical calculations confirm the equilibrium nature of CF₃COOHN₂O₅ interaction.

Language: English

DOI: 10.1016/j.mencom.2017.07.011

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