A. Yu. Kostyukovich, D. I. D'yachikhin, I. D. Grishin, I. A. Godovikov, A. F. Smol'yakov, F. M. Dolgushin, D. F. Grishin, I. T. Chizhevsky, E. V. Balagurova, “Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group”, Mendeleev Commun., 2017, Volume 27, Issue 4,Pages 392

This article is cited in 2 papers

Communications

Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group

A. Yu. Kostyukovich^a, D. I. D'yachikhin^a, I. D. Grishin^b, I. A. Godovikov^a, A. F. Smol'yakov^a, F. M. Dolgushin^a, D. F. Grishin^b, I. T. Chizhevsky^a, E. V. Balagurova^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.I. Lobachevsky State University of Nizhni Novgorod, Nizhni Novgorod, Russian Federation

Abstract: The reaction of the ruthenacarborane exo-nido-5,6,10-[Cl(Ph₃P)₂Ru]-5,6,10-(m-H)₃-10-H-7,8-(Ph)₂-7,8-C₂B₉H₆ with phenylacetylene in dichloromethane in the presence of triethylamine at ambient temperature affords exo-nido-5,6,10-[(Ph₃P)₂Ru]-5,6-(μ-H)₂-10-[μ-(PhC=CH)]-10-H-7,8-(Ph)₂-7,8-C₂B₉H₆ containing vinylene bridge group between carborane framework and ruthenium atom. Structure of the complex has been determined by X-ray diffraction study.

Language: English

DOI: 10.1016/j.mencom.2017.07.025