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JOURNALS // Mendeleev Communications // Archive
Mendeleev Commun., 2017 Volume 27, Issue 5, Pages 454–455 (Mi mendc2024)
This article is cited in 17 papers

Communications

Hybrid halobismuthates: a coordinated BrIBr– anion

V. Yu. Kotovab, N. P. Simonenkoa, A. B. Ilyukhina

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: A new organic-inorganic hybrid material containing bromobismuthate anions and bis(1-pyridino)hexane cations was synthesized and characterized. The reaction between (C16H22N2)2Bi2Br10 and HBr in the presence of HI vapor afforded (C16H22N2)3(BiBr6)2 as the main product and (C16H22N2)3(BiBr6)(BiBr7I) as a by-product containing the BrIBr– anion coordinated by bismuth.

Language: English

DOI: 10.1016/j.mencom.2017.09.007


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