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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2017 Volume 27, Issue 5, Pages 462–463 (Mi mendc2027)

This article is cited in 7 papers

Communications

Acetonylation of 5(3)-(1H-tetrazol-1-yl)-3(5)-nitro-1H-pyrazole

A. V. Kormanov, T. K. Shkineva, I. L. Dalinger

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: N-Acetonylation of 5(3)-(1H-tetrazol-1-yl)-3(5)-nitro-1H-pyrazole with bromoacetone in the presence of NaHCO3 at 60°C gave, along with expected isomeric N-acetonyl derivatives, a tricyclic product of the intramolecular electrophilic attack at the carbon atom of the tetrazole cycle.

Language: English

DOI: 10.1016/j.mencom.2017.09.010



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