V. I. Filyakova, N. S. Boltacheva, M. G. Pervova, N. V. Palysaeva, P. A. Slepukhin, A. B. Sheremetev, V. N. Charushin, “A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes”, Mendeleev Commun., 2017, Volume 27, Issue 5,Pages <nobr>464

This article is cited in 7 papers

Communications

A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes

V. I. Filyakova^a, N. S. Boltacheva^a, M. G. Pervova^a, N. V. Palysaeva^b, P. A. Slepukhin^a, A. B. Sheremetev^b, V. N. Charushin^a

^a I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A convenient direct synthesis of 1-aryl-3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes from the corresponding lithium 3-(polyfluoroalkyl)- 1,3-diketonates has been elaborated using sodium nitrite/acetic acid system under very mild conditions. The molecular structure of 4,4-difluoro-1-phenylbutane- 1,2,3-trione 2-oxime has been determined by X-ray crystallography.

Language: English

DOI: 10.1016/j.mencom.2017.09.011

	*Supplementary materials:*
		Supplementary_data_1.pdf	293.6 Kb