I. D. Burtsev, T. V. Dubinina, Ya. B. Platonova, A. D. Kosov, D. A. Pankratov, L. G. Tomilova, “Synthesis and spectral properties of iron(III) tetra-<i>tert</i>-butylphthalocyanine complexes”, Mendeleev Commun., 2017, Volume 27, Issue 5,Pages <nobr>466

This article is cited in 6 papers

Communications

Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes

I. D. Burtsev^a, T. V. Dubinina^ab, Ya. B. Platonova^a, A. D. Kosov^a, D. A. Pankratov^a, L. G. Tomilova^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: Two tetra-tert-butylphthalocyanine complexes of iron(III) were synthesized in high yields from the phthalocyanine ligand and iron(III) salts; the oxidation state of iron was confirmed by Mössbauer and EPR spectroscopy. The existence of an acid–base equilibrium during spectrophotometric titration was revealed. The ^t-BuPcFeCl complex catalyzed chlorination of benzene.

Language: English

DOI: 10.1016/j.mencom.2017.09.012