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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2017 Volume 27, Issue 5, Pages 490–492 (Mi mendc2037)

This article is cited in 8 papers

Communications

Synthesis of natural phaeosphaeride A and semi-natural phaeosphaeride B derivatives

V. V. Abzianidzea, K. P. Efimovab, E. V. Poluektovac, Yu. G. Trishinb, V. A. Kuznetsova

a Research Institute of Hygiene, Occupational Pathology and Human Ecology, Leningrad region, Russian Federation
b Saint-Petersburg State University of Industrial Technologies and Design, St. Petersburg, Russian Federation
c All-Russian Institute of Plant Protection, Federal Agency of Scientific Organizations, Pushkin, St. Petersburg, Russian Federation

Abstract: 6-O-Acylated phaeosphaeride A and phaeosphaeride B in reaction with secondary cyclic amines undergo stereospecific replacement of acyloxy group by pharmacophoric amino moiety. In case of chloroacetoxy derivative, chlorine displacement by such amines proceeds in the presence of triethylamine.

Language: English

DOI: 10.1016/j.mencom.2017.09.020



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