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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2017 Volume 27, Issue 6, Pages 567–569 (Mi mendc2061)

This article is cited in 6 papers

Communications

Reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide

G. A. Smirnova, P. B. Gordeeva, S. V. Nikitina, Yu. V. Nelyubinab, G. V. Pokhvisnevaa, T. V. Ternikovaa, O. A. Luk'yanova

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide results in corresponding [methylenebis(oxy)]bis(1-triazene 2-oxides). Treatment of 1-chloromethoxy-3-(2-hydroxyethyl)-3-methyl- 1-triazene 2-oxide with Me4NOH gives 16- and 24-membered intermolecular cyclization products.

Language: English

DOI: 10.1016/j.mencom.2017.11.009



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