G. A. Smirnov, P. B. Gordeev, S. V. Nikitin, Yu. V. Nelyubina, G. V. Pokhvisneva, T. V. Ternikova, O. A. Luk'yanov, “Reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide”, Mendeleev Commun., 2017, Volume 27, Issue 6,Pages <nobr>567

This article is cited in 6 papers

Communications

Reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide

G. A. Smirnov^a, P. B. Gordeev^a, S. V. Nikitin^a, Yu. V. Nelyubina^b, G. V. Pokhvisneva^a, T. V. Ternikova^a, O. A. Luk'yanov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide results in corresponding [methylenebis(oxy)]bis(1-triazene 2-oxides). Treatment of 1-chloromethoxy-3-(2-hydroxyethyl)-3-methyl- 1-triazene 2-oxide with Me₄NOH gives 16- and 24-membered intermolecular cyclization products.

Language: English

DOI: 10.1016/j.mencom.2017.11.009