A. V. Rassolov, D. S. Krivoruchenko, M. G. Medvedev, I. S. Mashkovsky, A. Yu. Stakheev, I. Svitanko, “Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study”, Mendeleev Commun., 2017, Volume 27, Issue 6,Pages 615

This article is cited in 17 papers

Communications

Diphenylacetylene hydrogenation on a PdAg /Al₂O₃ single-atom catalyst: an experimental and DFT study

A. V. Rassolov, D. S. Krivoruchenko, M. G. Medvedev, I. S. Mashkovsky, A. Yu. Stakheev, I. Svitanko

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The hydrogenation of diphenylacetylene (DPA) on palladium–silver catalysts with a single-atom structure was investigated. It has been shown experimentally that the reaction rate of alkene to alkane hydrogenation is substantially lower than the rate of DPA semi-hydrogenation. The kinetic barriers of all stages of hydrogenation were calculated by the DFT method.

Language: English

DOI: 10.1016/j.mencom.2017.11.026

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