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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 1, Pages 54–56 (Mi mendc2108)

This article is cited in 12 papers

Communications

Lanthanide complexes based on ethyl 2-hydroxymethylidene-3-oxobutanoate

Yu. S. Kudyakova, D. N. Bazhin, Ya. V. Burgart, V. I. Saloutin

I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Abstract: The reaction of europium(iii) or terbium(iii) chlorides with ethyl 2-hydroxymethylidene-3-oxobutanoate in the presence of 2,2’-bipyridine (2,2’-bipy) resulted in the luminescent complexes [LnL3]·2,2’-bipy (L = ethyl 2-hydroxymethylidene-3-oxobutanoate, Ln = Tbiii or Euiii), whose molecular structure has been determined by X-ray analysis.

Language: English

DOI: 10.1016/j.mencom.2016.01.021



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