A. E. Ivanova, Ya. V. Burgart, V. I. Saloutin, “Non-natural nucleosides bearing 4-aryldiazenylpyrazole aglycone”, Mendeleev Commun., 2016, Volume 26, Issue 2,Pages <nobr>106

This article is cited in 10 papers

Communications

Non-natural nucleosides bearing 4-aryldiazenylpyrazole aglycone

A. E. Ivanova, Ya. V. Burgart, V. I. Saloutin

I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Abstract: Ribosylation of 4-aryldiazenyl-3-R-5-R’-pyrazoles with 1,2,3,5-tetra-O-acetyl-β-D-ribofuranose in the presence of tin(IV) chloride gives α- and β-anomeric N-(2,3,5-tri-O-acetylribofuranosyl)-substituted derivatives. Their HPLC separation and deacetylation (MeOH, MeONa) affords 1-(β-D-ribofuranosyl)-3-R-5-R’-4-(aryldiazenyl)-1H-pyrazoles.

Language: English

DOI: 10.1016/j.mencom.2016.03.006

	*Supplementary materials:*
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