I. F. Sakharov, Z. N. Gafurov, V. M. Babaev, I. Kh. Rizvanov, A. B. Dobrynin, D. B. Krivolapov, Kh. R. Khayarov, O. G. Sinyashin, D. G. Yakhvarov, “First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2<i>’</i> -bipyridine)-2,4,6-tricyclohexylphenylnickel]”, Mendeleev Commun., 2016, Volume 26, Issue 2,Pages <nobr>131

This article is cited in 17 papers

Communications

First example of organonickel complex bearing three cyclic substituents in the σ-bonded aromatic ring: bromo[(2,2’ -bipyridine)-2,4,6-tricyclohexylphenylnickel]

I. F. Sakharov^ab, Z. N. Gafurov^ab, V. M. Babaev^a, I. Kh. Rizvanov^a, A. B. Dobrynin^a, D. B. Krivolapov^a, Kh. R. Khayarov^b, O. G. Sinyashin^a, D. G. Yakhvarov^ab

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Kazan Federal University, Kazan, Russian Federation

Abstract: The electrochemical reduction of [NiBr2(bpy)] (bpy is 2,2’-bipyridine) complex in the presence of 2,4,6-tricyclohexylphenylbromide (TchpBr) in undivided electrochemical cell supplied with a sacrificial nickel anode results in the one-pot formation of an organonickel complex [NiBr(Tchp)(bpy)] bearing three cyclic substituents in the s-bonded aromatic ring. The synthesized complex was characterized by various methods including single crystal X-ray analysis.

Language: English

DOI: 10.1016/j.mencom.2016.03.016

	*Supplementary materials:*
		Supplementary_data_1.pdf	568.6 Kb