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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 2, Pages 154–156 (Mi mendc2144)

This article is cited in 1 paper

Communications

Unusual stability of anionic associates in mixed solvents

A. A. Krotovaa, V. Yu. Kotovbc

a Institute of Natural Sciences, Moscow City Teacher’s Training University, Moscow, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: The ion associates [Fe(CN)6]4–, M+, [Cu edta]2–, which are observed in the UV-VIS spectra of K4[Fe(CN)6] + Na2[Cu edta] solutions as an absorption band at 500 nm, contain alkali metal cations, and they are more stable in water-organic solutions than in aqueous solutions.

Language: English

DOI: 10.1016/j.mencom.2016.03.025



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