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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2024 Volume 34, Issue 5, Pages 670–672 (Mi mendc215)

Communications

Photophysical properties of 2'-hydroxychalcones of 2-cinnamoyl-4-nitro-1-naphthol series

S. D. Batalin

Department of Chemistry, North-Caucasus Federal University, Stavropol, Russian Federation

Abstract: 2-Hydroxychalcones of 2-cinnamoyl-4-nitro-1-naphthol series were obtained by the condensation between 2-acetyl- 4-nitro-1-naphthol and benzaldehydes. The presence of the 4-positioned nitro group in the 1-hydroxy-2-naphthyl fragment contributes to the excited state intramolecular proton transfer (ESIPT) fluorescence of these 2-hydroxy- chalcones in the solid state. Compound with dimethyl- amino substituent, 2-(4-dimethylaminocinnamoyl)-4-nitro- 1-naphthol, also demonstrates ESIPT in solution.

Keywords: 2-hydroxychalcones, 2-cinnamoyl-4-nitro-1-naphthols, fluorescence, ESIPT, UV-Vis spectra, nitro compounds.

Language: English

DOI: 10.1016/j.mencom.2024.09.014



© Steklov Math. Inst. of RAS, 2025