A. A. Yakushev, A. D. Averin, O. A. Maloshitskaya, S. A. Syrbu, O. I. Koifman, I. P. Beletskaya, “Catalytic amination in the synthesis of hybrid polymacrocycles comprising porphyrin and azacrown ether moieties”, Mendeleev Commun., 2016, Volume 26, Issue 3,Pages <nobr>199–201</nobr>

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Mendeleev Commun., 2016 Volume 26, Issue 3, Pages 199–201 (Mi mendc2157)

This article is cited in 6 papers

Communications

Catalytic amination in the synthesis of hybrid polymacrocycles comprising porphyrin and azacrown ether moieties

A. A. Yakushev^a, A. D. Averin^ab, O. A. Maloshitskaya^b, S. A. Syrbu^c, O. I. Koifman^c, I. P. Beletskaya^ab

^a A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c Ivanovo State University of Chemistry and Technology, Ivanovo, Russian Federation

Abstract: Pd⁰-catalyzed amination of 3-bromobenzyl-substituted azacrown ethers with propane-1,3-diamine affords the 3-(3-aminopropyl)benzyl derivatives, whose reaction with meso-(bromophenyl)-substituted porphyrins leads to bis- and trismacrocyclic conjugates.

Language: English

DOI: 10.1016/j.mencom.2016.04.006

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