A. O. Terent'ev, M. Yu. Sharipov, A. P. Glinuskin, I. B. Krylov, D. V. Gaidarenko, G. I. Nikishin, “Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate”, Mendeleev Commun., 2016, Volume 26, Issue 3,Pages <nobr>226–227</nobr>

RUS ENG

JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 3, Pages 226–227 (Mi mendc2167)

This article is cited in 9 papers

Communications

Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate

A. O. Terent'ev^ab, M. Yu. Sharipov^ab, A. P. Glinuskin^c, I. B. Krylov^a, D. V. Gaidarenko^b, G. I. Nikishin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^c All-Russian Research Institute of Phytopathology, Bol'shiye Vyazemy, Moscow Region, Russian Federation

Abstract: β-Diketones and β-oxo esters are thiocyanated with the NaSCN/(NH₄)₂ Ce(NO₃)₆ system or with pre-generated dirhodanogen. Malonates undergo thiocyanation only with the NaSCN/(NH₄)₂ Ce(NO₃)₆ system.

Language: English

DOI: 10.1016/j.mencom.2016.05.001

Fulltext: PDF file (146 kB)
Cited by

	*Supplementary materials:*
		Supplementary_data_1.pdf	244.8 Kb

© Steklov Math. Inst. of RAS, 2025