A. V. Artem'ev, N. K. Gusarova, A. O. Sutyrina, Yu. V. Gatilov, B. A. Trofimov, “Synthesis of tris[2-(2-furyl)ethyl]phosphine its chalcogenides and Pd<sup><sc>ii</sc></sup> complex”, Mendeleev Commun., 2016, Volume 26, Issue 4,Pages <nobr>314–316</nobr>

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Mendeleev Commun., 2016 Volume 26, Issue 4, Pages 314–316 (Mi mendc2198)

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Communications

Synthesis of tris[2-(2-furyl)ethyl]phosphine its chalcogenides and Pdⁱⁱ complex

A. V. Artem'ev^a, N. K. Gusarova^a, A. O. Sutyrina^a, Yu. V. Gatilov^bc, B. A. Trofimov^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: Nucleophilic addition of PH₃ to 2-vinylfuran in the KOH/DMSO(H₂O) suspension affords 65% of tris[2-(2-furyl)ethyl]-phosphine, whose treatment with H₂O₂, Se or PdCl gives the corresponding phosphine oxide, selenide and complex of trans-[Pd(L)₂Cl₂] type in good to excellent yields.

Language: English

DOI: 10.1016/j.mencom.2016.07.016

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