N. V. Sergienko, A. A. Korlyukov, D. E. Arkhipov, V. V. Novikov, M. A. Eskova, B. G. Zavin, “Metallosiloxanes containing period 5 transition metals: synthesis and X-ray studies of three cadmium siloxanes”, Mendeleev Commun., 2016, Volume 26, Issue 4,Pages <nobr>344

This article is cited in 16 papers

Communications

Metallosiloxanes containing period 5 transition metals: synthesis and X-ray studies of three cadmium siloxanes

N. V. Sergienko, A. A. Korlyukov, D. E. Arkhipov, V. V. Novikov, M. A. Eskova, B. G. Zavin

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Hydrolysis of PhSi(OEt)₃ in the presence of MOH (M = K, Na) and CdBr₂ affords new cadmium siloxanes of sandwich type, whose encapsulated species (Br⁻, H₂O, OH) are defined by the solvent used for synthesis and crystallization.

Language: English

DOI: 10.1016/j.mencom.2016.07.026