K. A. Nikitina, K. E. Metlushka, D. N. Sadkova, L. N. Shaimardanova, V. A. Alfonsov, “Synthesis of α-amino phosphonates by diastereoselective addition of diethyl phosphite sodium salt to aldimines derived from Betti base”, Mendeleev Commun., 2016, Volume 26, Issue 5,Pages <nobr>395

This article is cited in 5 papers

Communications

Synthesis of α-amino phosphonates by diastereoselective addition of diethyl phosphite sodium salt to aldimines derived from Betti base

K. A. Nikitina^a, K. E. Metlushka^ab, D. N. Sadkova^a, L. N. Shaimardanova^a, V. A. Alfonsov^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b A.M. Butlerov Chemistry Institute, Kazan Federal University, Kazan, Russian Federation

Abstract: A diastereoselective (de 80–92%) synthesis of α-amino phosphonates was accomplished by reaction of diethyl phosphite sodium salt with 3-R-1-phenyl-2,3-dihydro-1H-naphth[1,2-e]-[1,3]oxazines being the products of aminoacetalization of aldehydes with 1-(α-aminobenzyl)-2-naphthol (Betti base).

Language: English

DOI: 10.1016/j.mencom.2016.09.009

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