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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 6, Pages 491–493 (Mi mendc2256)

This article is cited in 18 papers

Communications

Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes

A. A. Chamkin, A. M. Finogenova, Yu. V. Nelyubina, J. N. Laskova, A. R. Kudinov, D. A. Loginov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reactions of [(η5-indenyl)IrI2]η with CpTl or arenes in the presence of AgBF4 afford [(η5-indenyl)IrCp]+ or [(η5-indenyl)Ir(arene)]2+ cations (arene = benzene, mesitylene, durene or hexamethylbenzene); the structures of (η5-indenyl)-Ir(C2H4)2 and [(η5-indenyl)IrCp]PF6 were characterized by X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2016.11.010



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