A. A. Chamkin, A. M. Finogenova, Yu. V. Nelyubina, J. N. Laskova, A. R. Kudinov, D. A. Loginov, “Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes”, Mendeleev Commun., 2016, Volume 26, Issue 6,Pages 491

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Communications

Iodide [(η⁵-indenyl)IrI₂]_n: an effective precursor to (indenyl)iridium sandwich complexes

A. A. Chamkin, A. M. Finogenova, Yu. V. Nelyubina, J. N. Laskova, A. R. Kudinov, D. A. Loginov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reactions of [(η⁵-indenyl)IrI₂]_η with CpTl or arenes in the presence of AgBF₄ afford [(η⁵-indenyl)IrCp]⁺ or [(η⁵-indenyl)Ir(arene)]²⁺ cations (arene = benzene, mesitylene, durene or hexamethylbenzene); the structures of (η⁵-indenyl)-Ir(C₂H₄)₂ and [(η⁵-indenyl)IrCp]PF₆ were characterized by X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2016.11.010