P. V. Markov, G. O. Bragina, A. V. Rassolov, I. S. Mashkovsky, G. N. Baeva, O. P. Tkachenko, I. A. Yakushev, M. N. Vargaftik, A. Yu. Stakheev, “Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes”, Mendeleev Commun., 2016, Volume 26, Issue 6,Pages <nobr>494

This article is cited in 28 papers

Communications

Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes

P. V. Markov^a, G. O. Bragina^a, A. V. Rassolov^a, I. S. Mashkovsky^a, G. N. Baeva^a, O. P. Tkachenko^a, I. A. Yakushev^b, M. N. Vargaftik^b, A. Yu. Stakheev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The 1% Pd–1% In / MgAl₂O₄ catalyst demonstrated excellent selectivity in the semi-hydrogenation of internal 1-phenylprop-1-yne, which exceeded the selectivity of a commercial Lindlar catalyst and reference monometallic 0.5% Pd/MgAl₂O₄ catalyst due to Pd–In alloy formation.

Language: English

DOI: 10.1016/j.mencom.2016.11.011