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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 6, Pages 497–499 (Mi mendc2258)

This article is cited in 10 papers

Communications

Synthesis of dimethyl carbonate from methanol and CO2 on the SnO2/Al2O3-based catalyst

A. A. Greish, E. D. Finashina, O. P. Tkachenko, E. V. Shuvalova, L. M. Kustov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The SnO2 /Al2O3 catalyst promoted with CuCl2, ZnCl2, KF exhibited high activity in the synthesis of dimethyl carbonate from methanol and CO2 (130°C, 16bar, 4h) providing the 17.8% yield of the product with ca. 99% selectivity.

Language: English

DOI: 10.1016/j.mencom.2016.11.012



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