A. V. Babkin, A. F. Asachenko, D. V. Uborsky, D. S. Kononovich, V. V. Izmer, V. A. Kudakina, V. A. Shnaider, N. E. Shevchenko, A. Z. Voskoboynikov, “Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium”, Mendeleev Commun., 2016, Volume 26, Issue 6,Pages 555

This article is cited in 3 papers

Communications

Preparation of N-phenyl-p-phenylenediamine by coupling of aniline and nitrobenzene in KOH–poly(ethylene glycol) medium

A. V. Babkin^a, A. F. Asachenko^b, D. V. Uborsky^a, D. S. Kononovich^a, V. V. Izmer^a, V. A. Kudakina^a, V. A. Shnaider^a, N. E. Shevchenko^a, A. Z. Voskoboynikov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A novel protocol for efficient coupling of nitrobenzene and aniline in poly(ethylene glycol) medium in the presence of KOH giving diphenylamine derivatives has been developed, to enable the exclusion of the toxic tetramethylammonium hydroxide catalyst commonly used in the rubber antidegradant industry.

Language: English

DOI: 10.1016/j.mencom.2016.11.033

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