B. A. Trofimov, E. Yu. Schmidt, I. A. Bidusenko, N. A. Cherimichkina, “Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension”, Mendeleev Commun., 2015, Volume 25, Issue 1,Pages <nobr>17

This article is cited in 4 papers

Communications

Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension

B. A. Trofimov, E. Yu. Schmidt, I. A. Bidusenko, N. A. Cherimichkina

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: 1,5-Diphenylpentane-1,5-dione reacts (50 mol% KOH in DMSO, 70°C, 3h) with phenylacetylene in a domino manner to afford 3-benzoyl-2-benzyl-1-phenylcyclopenten-1-ol and its debenzoylated derivative in 66 and 25% yields, respectively.

Language: English

DOI: 10.1016/j.mencom.2015.01.005