D. G. Yakhvarov, E. A. Trofimova, A. B. Dobrynin, T. P. Gerasimova, S. A. Katsyuba, O. G. Sinyashin, “First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study”, Mendeleev Commun., 2015, Volume 25, Issue 1,Pages 27

This article is cited in 7 papers

Communications

First neutral dinuclear cobalt complex formed by bridging [μ-O₂P(H)R]^– ligands: synthesis, X-ray crystal structure and quantum-chemical study

D. G. Yakhvarov^ab, E. A. Trofimova^a, A. B. Dobrynin^a, T. P. Gerasimova^a, S. A. Katsyuba^a, O. G. Sinyashin^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and 9-anthrylphosphinic acid AntP(O)(OH)H (Ant = 9-anthryl) leads to the first example of a neutral dinuclear cobalt(ii) complex {Co₂Br₂[μ-O₂P(H)Ant]₂(bpy)₂} formed by two bridging [μ-O₂P(H)Ant]^– ligands. The complex has been characterized by X-ray diffraction analysis and quantum-chemical calculations.

Language: English

DOI: 10.1016/j.mencom.2015.01.009

	*Supplementary materials:*
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