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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 1, Pages 29–31 (Mi mendc2289)

This article is cited in 13 papers

Communications

Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+

D. S. Perekalin, N. V. Shvydkiy, Yu. V. Nelyubina, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The cation [Cp*Ru(C10H8)]+ exchanges naphthalene for various ligands under near-UV (365nm) or visible light irradiation giving the half-sandwich complexes [Cp*RuL3]+ [L = P(OMe)3, 1,3,5-triaza-7-phosphaadamantane, ButNC], [Cp*Ru(dppe)(MeCN)]+, Cp*Ru(CO)2Cl, Cp*Ru[tris(pyrazolyl)borate] and [Cp*Ru(C6H6)]+ in 80–95% yields.

Language: English

DOI: 10.1016/j.mencom.2015.01.010



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