Mendeleev Commun., 2015 Volume 25, Issue 1, Pages 44–46
(Mi mendc2295)
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11 papers
Communications Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides V. K. Brel ab ,
A. V. Samet c ,
L. D. Konyushkin c ,
A. I. Stash d ,
V. K. Belsky d ,
V. V. Semenov c a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation d L. Ya. Karpov Institute of Physical Chemistry, Moscow, Russian Federation
Abstract:
Simple chiral precursors for the preparation of methylene-expanded C-nucleosides were developed, using as key steps pyrolysis of cellulose to levoglucosenone followed by hydrogenation and introduction of vinyl and ethynyl fragments to the 2-position.
Language: English
DOI:
10.1016/j.mencom.2015.01.016
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