A. I. Uraev, L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, K. Yu. Suponitsky, D. A. Garnovskii, V. V. Lukov, V. A. Kogan, “Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set”, Mendeleev Commun., 2015, Volume 25, Issue 1,Pages 62

This article is cited in 8 papers

Communications

Crystal structure and magnetic properties of a tetranuclear carbonate-bridged Cu^II complex with a Schiff base compartmental ligand with the N₂OS₂ donor set

A. I. Uraev^a, L. D. Popov^a, S. I. Levchenkov^b, I. N. Shcherbakov^a, K. Yu. Suponitsky^c, D. A. Garnovskii^b, V. V. Lukov^a, V. A. Kogan^a

^a Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A carbonate-bridged tetranuclear Cu^II complex of the general formula [(Cu₂L)₂CO₃]·2MeCN (L is triply deprotonated Schiff base condensation product of 1,3-diaminopropan-2-ol and 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole) has been obtained by the slow crystallization of dinuclear complex [(Cu₂L)CCl₃COO] from acetonitrile and studied by X-ray diffraction and low-temperature magnetic measurements.

Language: English

DOI: 10.1016/j.mencom.2015.01.023