I. S. Ryzhkina, Yu. V. Kiseleva, L. I. Murtazina, O. A. Mishina, A. P. Timosheva, S. Yu. Sergeeva, V. V. Baranov, A. N. Kravchenko, A. I. Konovalov, “Self-organization and chirality in the high dilution solutions of glycoluril enantiomers with (R)- and (S)-methionine moieties”, Mendeleev Commun., 2015, Volume 25, Issue 1,Pages 72

This article is cited in 6 papers

Communications

Self-organization and chirality in the high dilution solutions of glycoluril enantiomers with (R)- and (S)-methionine moieties

I. S. Ryzhkina^a, Yu. V. Kiseleva^a, L. I. Murtazina^a, O. A. Mishina^a, A. P. Timosheva^a, S. Yu. Sergeeva^a, V. V. Baranov^b, A. N. Kravchenko^b, A. I. Konovalov^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The high dilution (1×10^-15–1×10^-5 mol dm^-3) solutions of glycolurils containing an (S)-methionine moiety are capable of space-time self-organization to give nanoassociates, unlike the solutions of glycolurils with an (R)-methionine moiety. The formation of supra- molecular domains in the solutions at concentrations of 1×10^-3–1×10^-2 mol dm^-3 is responsible for a transition from molecular to supramolecular chirality.

Language: English

DOI: 10.1016/j.mencom.2015.01.027

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