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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 2, Pages 93–95 (Mi mendc2309)

This article is cited in 6 papers

Communications

Syntheses of α-cyano substituted oximes from terpenic hydrocarbons via nitroso chlorides: X-ray structures of 3-cyanocaran-4-one oxime, 2-cyanopinan-3-one oxime and 1-cyano-p-menth-8-en-2-one oxime

S. N. Bizyaeva, Yu. V. Gatilova, A. V. Tkachevab

a N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: (+)-3-Carene-, (S)-(–)-α-pinene- and (R)-(+)-limonene-derived α-nitroso chlorides on treatment with an excess of acetone cyanohydrin afford the corresponding α-cyano oximes, whose structure was solved by X-ray crystallography.

Language: English

DOI: 10.1016/j.mencom.2015.03.003



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