D. V. Muratov, A. S. Romanov, A. R. Kudinov, “Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+”, Mendeleev Commun., 2015, Volume 25, Issue 2,Pages 109

This article is cited in 2 papers

Communications

Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C₅Me₄CH₂)]+

D. V. Muratov, A. S. Romanov, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The cationic complex [Cp*Ru(C₅Me₄CH₂)]⁺ reacts with Et₃N primarily giving the ammonium salt [Cp*Ru(C₅Me₄CH₂NEt₃)]⁺. The prolonged standing of the reaction mixture results in the formation of the ether Cp*Ru(C₅Me₄CH₂OCH₂C₅Me₄)RuCp*. The reaction of [Cp*Ru(C₅Me₄CH₂)]⁺ with PhNEt₂ leads to the electrophilic aromatic substitution product [Cp*Ru(C₅Me₄CH₂C₆H₄NHEt₂)]⁺.

Language: English

DOI: 10.1016/j.mencom.2015.03.009

	*Supplementary materials:*
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