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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 2, Pages 109–110 (Mi mendc2315)

This article is cited in 2 papers

Communications

Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+

D. V. Muratov, A. S. Romanov, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The cationic complex [Cp*Ru(C5Me4CH2)]+ reacts with Et3N primarily giving the ammonium salt [Cp*Ru(C5Me4CH2NEt3)]+. The prolonged standing of the reaction mixture results in the formation of the ether Cp*Ru(C5Me4CH2OCH2C5Me4)RuCp*. The reaction of [Cp*Ru(C5Me4CH2)]+ with PhNEt2 leads to the electrophilic aromatic substitution product [Cp*Ru(C5Me4CH2C6H4NHEt2)]+.

Language: English

DOI: 10.1016/j.mencom.2015.03.009



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