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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 2, Pages 119–120 (Mi mendc2319)

This article is cited in 4 papers

Communications

Microwave-assisted cyanation of 3-bromo-3-(1-hydroxyalkyl)benzo[b]selenophene derivatives

P. Arsenyan, E. Paegle, S. Belyakov

Latvian Institute of Organic Synthesis, Riga, Latvian Republic

Abstract: Microwave-assisted palladium-catalyzed cyanation of 3-bromo-2-(1-hydroxyalkyl)benzo[b]selenophene affords 3-cyano derivatives. Raising the temperature promotes formation of 2-(1-alkenyl)-3-carbamoyl isomers through intramolecular transfer of water.

Language: English

DOI: 10.1016/j.mencom.2015.03.013



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